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  4. Provinces and territories of Canada - Wikipedia

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    Canada has ten provinces and three territories that are sub-national administrative divisions under the jurisdiction of the Canadian Constitution.In the 1867 Canadian Confederation, three provinces of British North America—New Brunswick, Nova Scotia, and the Province of Canada (which upon Confederation was divided into Ontario and Quebec)—united to form a federation, becoming a fully ...

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  6. Recent growth. Between 2016 and 2021, the five CMAs with the highest percentage growth were located in British Columbia and Southern Ontario. The five CMAs with the lowest percentage growth were in Quebec, Alberta, Northern Ontario and Newfoundland and Labrador. There were no CMAs for which negative growth was recorded in the 2021 census.

  7. Tadalafil - Wikipedia

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    Tadalafil is an annulated 2,5-diketopiperazine. [25] It is also a 1,2,3,4-tetrahydro-β-carboline. Tadalafil can be synthesized starting from (D)-tryptophan methyl ester and piperonal via a Pictet–Spengler reaction. This is followed by condensations with chloroacetyl chloride and methylamine to complete the diketopiperazine ring: [26]

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